Voyages Sncf UK is a very good source of information for rail travel in France and will allow you to book on line. There is also a Motorail service (French page) if you want to take your car with you. You can phone to make this arrangement (use the first UK page for this) up to 6 months in advance or you can book online by filling in the form on the French page. You have to load your car at the Paris Bercy Station for this service and then you take a separate passenger train to get yourself to the same destination to pick it up the following day. If you find the whole thing a little confusing then it is better to call the number on the UK site to talk it through.
You can also visit the French rail operators http://www.tgv.com to explore other options for rail travel.
Call 0033 (0)4 68 94 08 66 or email email@example.com to make a booking
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